Cashew Nut Shell Liquid (CNSL)

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  • Cashew Nut Shell Liquid (CNSL) is a unique, industrial-grade oil extracted from the hard shell surrounding cashew nuts. Unlike conventional edible oils, CNSL possesses distinctive chemical properties that make it a valuable resource across multiple industries, including coatings, adhesives, automotive, and specialty chemicals. With its rich composition of anacardic acid, cardanol, and cardol, CNSL is a sustainable and renewable material with high industrial utility.

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Composition and Chemical Properties of CNSL

The primary chemical constituents of Cashew Nut Shell Liquid include:

  • Anacardic Acid (60-65%): The dominant component, known for its antibacterial, antifungal, and antioxidant properties. It has potential applications in pharmaceuticals and personal care products due to its anti-inflammatory effects.
  • Cardanol (20-25%): A derivative of anacardic acid obtained through thermal processing. Cardanol is widely used in the manufacture of high-performance resins, coatings, electrical insulators, and corrosion-resistant materials.
  • Cardol (10%): A phenolic compound with reactive properties, primarily used in adhesives, anti-corrosion coatings, and chemical synthesis.
  • Minor Polymers and Residues (5%): These trace elements contribute to CNSL’s overall functionality in industrial applications.

Additionally, CNSL contains long-chain hydrocarbons, which enhance its ability to undergo chemical modifications. These modifications allow it to serve as a precursor for bio-based monomers used in polymer chemistry, fuel additives, and specialty lubricants. Due to its multifunctional nature, CNSL is gaining increased attention as an alternative to petrochemical derivatives.

Property

Test Method

Result

Unit

Total Volatile Loss (105°C / 3hrs)

ASTM D1644-01 (2012)

0.6

% (m/m)

Net Heat of Combustion

ASTM D240-19

9048.5

kcal/kg

Density at 25°C

ASTM D4052-22

0.9530

kg/L

Density at 25°C

ASTM D1298-12b (2017)

0.9530

kg/L

Dynamic Viscosity at 25°C

ASTM D7042-21a

139.7

mPa.s

Sediment by Extraction

ASTM D473-22

0.83

% (m/m)

Measured pH Value

Ref. ASTM E70-19

7.78

pH

Water Content

ASTM D95-23

0.30

% (v/v)

Remark:

  • % (m/m) = % (w/w) = % wt = % mass
  • % (v/v) = % vol = % volume

COA of Cashew Nut Shell Liquid (CNSL)

CNSL Extraction and Processing

The extraction of CNSL depends on the method used, which influences its chemical composition:

  1. Cold Press Extraction: This method yields CNSL with a high anacardic acid content (approximately 70%), making it ideal for pharmaceutical and biopesticide applications.
  2. Heat Treatment: Heating CNSL decarboxylates the anacardic acids, converting them into cardanol and enhancing its usability in industrial applications.
  3. Distillation: Further purification through distillation increases cardanol concentration (up to 78%) while reducing cardol content to around 8%, making it suitable for high-performance coatings and adhesives.
  4. Fractional Distillation: A more refined process that allows separation of different phenolic fractions, optimizing CNSL for specialized applications such as high-end epoxy resins and bio-based polymers.
  5. Solvent Extraction: This method provides a purer yield of specific compounds, particularly beneficial for pharmaceutical applications requiring high levels of anacardic acid.
cashew-nut-shell-liquid-1

CNSL Extraction and Processing

How CNSL Is Applied in Industrial Settings

Due to its exceptional chemical structure, CNSL is extensively used in various industries:

  • Paints and Coatings: CNSL-based coatings provide superior corrosion resistance and durability, making them ideal for marine, automotive, and industrial applications.
  • Polymer and Resin Production: The phenolic structure of CNSL-derived cardanol enhances the flexibility and durability of epoxy resins, alkyd resins, and phenolic resins.
  • Adhesives and Sealants: CNSL contributes to high-performance adhesives with excellent bonding strength, chemical resistance, and thermal stability.
  • Friction Materials: The residue from CNSL distillation is utilized in manufacturing friction particles for automotive brake linings, improving their wear resistance and thermal stability.
  • Pharmaceutical and Personal Care: Anacardic acid exhibits antibacterial and antifungal properties, making it a potential ingredient in medicinal formulations and skincare products.
  • Bio-based Lubricants and Fuel Additives: CNSL derivatives are explored as eco-friendly lubricants, anti-oxidants, and diesel engine fuel alternatives.
cashew-nut-shell-liquid-2

How CNSL Is Applied in Industrial Settings

Safety and Handling of CNSL

Raw CNSL contains anacardic acid and organic sulfur compounds, which can cause skin irritation and allergic reactions similar to poison ivy. To ensure safe handling, CNSL undergoes thermal processing or chemical treatment to neutralize its dermatogenic properties.

When transporting CNSL, it is classified based on its processing state:

  • Raw CNSL: Considered hazardous cargo, requiring specialized handling and safety measures.
  • Processed CNSL: Safer for commercial use, commonly transported in dedicated storage tanks to prevent contamination.

Storage conditions play a crucial role in maintaining CNSL quality. It should be stored in airtight, corrosion-resistant containers at stable temperatures to prevent oxidative degradation. Proper ventilation and safety measures should be in place to minimize exposure to vapors, which can be irritating to the respiratory system

cashew-nut-shell-liquid-3

Safety and Handling of CNSL

Environmental and Sustainability Benefits of CNSCNSL

CNSL is a renewable resource with significant environmental benefits:

  • Reduction of Petroleum Dependency: CNSL-derived products serve as sustainable alternatives to petroleum-based chemicals.
  • Low Carbon Footprint: The cashew industry generates CNSL as a byproduct, minimizing waste and maximizing resource efficiency.
  • Biodegradability: CNSL-based materials break down naturally over time, reducing environmental impact.
  • Waste Valorization: The utilization of cashew nutshells for CNSL production exemplifies circular economy principles, where agricultural waste is converted into valuable industrial materials.
  • Carbon Sequestration Potential: CNSL-based products have been shown to contribute to carbon sequestration by replacing petroleum-based alternatives that release high levels of greenhouse gases.

Conclusion

Cashew Nut Shell Liquid (CNSL) is an innovative, bio-based industrial material with immense potential in coatings, resins, adhesives, and specialty chemicals. Its renewable nature, coupled with its versatile applications, makes it a valuable alternative to petroleum-based chemicals. With ongoing advancements in CNSL processing and utilization, this natural oil continues to shape sustainable industrial solutions worldwide.

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